B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems     

Wolfram Kloppmann  Haim Chikurel  Géraldine Picot  Joseph Guttman  Marie Pettenati  Avi Aharoni  Catherine Guerrot  Romain Millot  Irina Gaus  Thomas Wintgens 《Applied Geochemistry》2009

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.  相似文献   

Potential impact of climate change on aquatic insects: A sensitivity analysis for European caddisflies (Trichoptera) based on distribution patterns and ecological preferences   总被引：1，自引：1，他引：0  

Daniel Hering  Astrid Schmidt-Kloiber  John Murphy  Sofie Lücke  Carmen Zamora-Muñoz  Manuel Jesús López-Rodríguez  Thomas Huber  Wolfram Graf 《Aquatic Sciences - Research Across Boundaries》2009,71(1):3-14

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Active Galactic Nuclei     

Martin Haas  Peter Biermann  Rolf Chini  Jochen Heidt  Wolfram Kollatschny  Helmut Meusinger  Ralf Siebenmorgen 《Astronomische Nachrichten》2007,328(7):665-680

F11 Jets, supernovae, gammabursts – more light for theory? F35 A Direct Comparison of the QSO Samples from VPMS and SDSS F36 Gravitational Microlensing Simulations and Ensemble Broad‐Band Variability of the QSOs from VPMS F42 Luminosity function of low redshift quasars F43 Star Formation around Active Galactic Nuclei – Results from near infrared observations F58 High‐Redshift Quasars as Probes of Early Star Formation F66 On the dust emission of Seyfert nuclei F72 Propagation of Very Light MHD Jets F78 Giant Outflows in MassiveHigh‐z Radio Galaxies: Direct Evidence for AGNFeedback in the Early Universe F89 Lowfrequency mapping of ‘normal’ FR II radio galaxies: Resolving the puzzle of X‐shaped radio sources F90 Nature of X‐shaped radio sources: A statistical approach F100 Cosmological growth of Supermassive Black Holes: constraints on kinetic and radiative energy feedback F107 Molecular Tori in AGN F136 Electron‐Ion Recombination Rate Coefficients of Iron M‐Shell Ions for X‐Ray Astronomy F139 Hydrodynamic models of obscuring tori F145 The unique BL Lac Object S5 0716+714 F158 On the Cluster Environment of the BL Lac Object OJ 287 F179 The circumnuclear dust in nearby AGN resolved by mid‐infrared interferometry F184 NIR‐imaging of SDSS BL Lac objects F190 Blazar Observations in the TeV energy range with the MAGIC Telescope F198 Gas Inflow Rates in Nearby AGN Galaxies F202 Two zone SSC model for blazar jets F215 Long‐termVHE γ ‐ray monitoring of bright blazars with a dedicated telescope F218 Long termmonitoring of bright TeV Blazars with the MAGIC telescope F220 Fifteen Blazars in Very‐High Energy Gamma Rays: A Comparative Study F229 Numerical calculation of blazar spectra. Application to 1 ES 1218+30.4 F230 Blazar spectral energy distributions corrected for gamma ray attenuation F240 Observation of PG 1553+113 with the MAGIC Telescope F243 VHE Gamma‐Ray Flare of PKS2155‐304 detected by the MAGIC telescope F245 Observations of 3C279 with the MAGIC Telescope F258 Diffraction limited near infrared imaging spectroscopy of the NLR of NGC4151  相似文献   

Map of sediment distribution in the western baltic sea (1 :100,000), sheet falster — møn     

Franz Tauber  Wolfram Lemke  Rudolf Endler 《Ocean Dynamics》1999,51(1):5-32

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Changes of cloud microphysical properties during the transition from supercooled to mixed-phase conditions during CIME     

Stephan Mertes  Alfons Schwarzenbck  Paolo Laj  Wolfram Wobrock  Jean-Marc Pichon  Giordano Orsi  Jost Heintzenberg 《Atmospheric Research》2001,58(4)

A ground-based seeding experiment using carbon dioxide and propane sprayed from pressurized bottles was carried out under supercooled cloud conditions on a small spatial and short time scale. Water vapor deposition on the artificially generated dry ice and propane ice germs as the main ice formation process (nucleation and growth) is consistent with the experimental results. After nucleation, diffusional growth of the ice particles, partly at the expense of evaporating small droplets, was identified during the mixing of the seeding line with the ambient supercooled cloud. Within the seeding plume, ice water contents up to 80% of the total condensed water are observed, although the size of the formed ice particles did not exceed 25 μm. From the changes of the ice and supercooled liquid phase with time under mixed-phase conditions, liquid water content (LWC) evaporation, ice water content (IWC) formation, and ice crystal growth rates are estimated, which are not affected by the artificial nucleation process. Thus, these rates are assessed to be applicable for a growing ice phase of small ice particles in a young mixed-phase cloud, where other growth mechanisms, like riming or aggregation, are negligible.  相似文献   

Modelling cloud processing of aerosol during the ACE‐2 HILLCLOUD experiment     

Michael L. Flynn  Keith N. Bower  Thomas W. Choularton  Wolfram Wobrock  Jyrki M. Mäkelä  Bengt Martinsson  Göran Frank  Hans&#;Christen Hansson  Hans Karlsson  Paolo Laj 《Tellus. Series B, Chemical and physical meteorology》2000,52(2):779-800

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Calcite patchiness in Lake Constance as viewed by LANDSAT-TM     

Agnes G. Pulvermüller  Joachim Kleiner  Wolfram Mauser 《Aquatic Sciences - Research Across Boundaries》1995,57(4):338-349

Calcite precipitation is a phenomenon occuring in most hardwater lakes world-wide. On May 5th, 1990, a whiting in Lake Constance was observed by LANDSAT for the first time. Physical, chemical and biological ground data sets prove that the observed structures are caused by calcite precipitation. This satellite observation provides information about the patchiness of calcite crystals suspended in the surface water of the lake western basin.  相似文献   

Untersuchungen am Meteoriten von Borkut und anderen Chondriten über Form,Aufbau und Entstehung der Chondren     

Dr. Wolfram Keidel 《Contributions to Mineralogy and Petrology》1965,11(5):487-506

Zusammenfassung Durch Ausmessung der Chondrenquerschnitte an Anschliffen van sechs Chondriten und Messungen an isolierten Chondren von Borkut ergab sich:Die Häufigkeitsverteilung der Chondren ist symmetrisch, das Maximum liegt bei einem Durchmesser von 0,6–0,8 mm. Chondren Bind Rotationsellipsoide oder allgemeine Ellipsoids und zum geringen Teil Kugeln (etwa 12%). Kleinere Chondren sind kugelähnlicher als große. Die ellipsoidischen Chondren zeigen bei Borkut and Bluff sine deutliche Einregelung.Der Chondrit Borkut besteht aus Bronzit, Olivin, Nickeleisen, Troilit, Chromic und Glas mit Feldspatmikrolithen. Er enthält Pyroxen-, PyroxenOlivin-und Olivinchondren. Des Orthopyroxen ist ein Bronzit mit 24,5 Mol.-% FeSiO₃, der Olivin enthält 31 Mol.-% Fe₂S0₄.Das spezifische Gewicht ist 3,609 g/cm³, das Porenvolumen beträgt 19,06%.Der Gesamtmeteorit und die Chondren wurden getrennt chemisch analysiert. Nach Chernismus und Mineralbestand gehört Borkut dem L-Typ der Chondrite an.Die Pyroxenchondren von l3orkut bestehen aus Lamellensystemen nach (100) oder (101) and einem Feldspatglas mit Mikrolithen. Sie haben sich ebenso wie gemischte and Olivinchondren als Tröpfchen aus einer Schmelze gebildet, die schnell abgekühlt wurden. Die verschiedenen Chondrentypen können dadurch entstehen, daß ein Magma mit bereits ausgeschiedenen Olivinkristallen zu kleinen Tröpfchen zerrissen wurde, wobei Tröpfchen mit Olivinkristallen (gemischte Chondren) und solche ohne Olivin (Pyroxenchondren) entstanden.

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Measurements of cross-sections of chondrules in. sections of 6 chondrites and measurements of isolated chondrules from Borkut yielded te following results:The grain size distribution of chondrules is symmetrical, its maximum being at a diameter of 0.6 to 0.8 mm. Chondrules are rotation ellipsoids or ordinary ellipsoids, a minor part are spherules (some 12%). Smaller chondrules form more perfect spherules than bigger ones. Elliptical chondrules in Borkut and Bluff show an evident orientation.The chondrite Borkut consists of bronzite, olivine, nickeliron, troilite, chromite, and glass with microlithic felspar. It contains pyroxene chondrules, pyroxene olivine chondrules, and olivine chondrules. The orthopyroxene is a bronzite containing 24.5 mol.-% FeSiO₃, the olivine contains 31 mol.-% Fe₂SiO₄,Its specific gravity is 3.609 g/cm³, its porosity amounts to .19.06%.The whole meteorite and the chondrules had been chemically analyzed separately. According to its chemical composition and mineral content, Borkut has to be classified under type L of chondrites. The pyroxene chondrules of Borkut consist of systems of lamellae parallel (100) or (101) and of felspar glass with microlithic crystals. They, as well as mixed chondrules and olivine chondrules, originated from a melt as droplets, which cooled down rapidly. The different types of chondrules may originate, when magma containing already crystallized olivine is disrupted to droplets; the result is then either droplets containing olivine crystals (mixed chondrules) or droplets without olivine (pyroxene chondrules).

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Mineralbestand und Entstehung des „Porzellanjaspis” von Epterode (Nordhessen)     

Dr. Wolfram Echle 《Contributions to Mineralogy and Petrology》1964,10(1):32-41

Zusammenfassung Es wurden Lagerung, Mineralbestand und Genese eines Gesteins untersucht, das bei Epterode, Nordhessen, auf kleinem Raum vorkommt und den Namen Porzellanjaspis führt.Das in bunten Farben aufgeschlossene, meist sehr harte und feinkörnige Material ist, im Gegensatz zu früheren Annahmen, primär gelagert und verdankt seinen Mineralbestand — Quarz, Cristobalit, Cordierit, Mullit, Spinell, Korund und Glasphase — einer Erwärmung oligozäner Sedimente in situ auf mindestens 1000° C. Einige kleine Halden an der Südseite sind erst später aus schon gebranntem Material entstanden. Seitliche Übergänge in unveränderten oligozänen Ton und Sand sind vorhanden. Der Mineralbestand dieser Tone (Quarz, Illit, Kaolinit, möglicherweise auch Montmorillonit) läßt sich mit den Hochtemperaturphasen und der chemischen Analyse des untersuchten Gesteins in Einklang bringen.Die Entstehung ist nicht, wie z. T. bisher angenommen, auf Alaunbereitung zurückzuführen, da der Haldencharakter entfällt, sondern auf einen Schwelbrand liegender tertiärer Kohle vor der Abtragung der oligozänen Sedimente. Der dabei entstandene Härtling widerstand der Abtragung besser als die flankierenden normalen Tone und Sande. Mit dieser Deutung läßt sich die aus dem Gesamtbild der tertiären Ablagerungen der Umgebung herausfallende morphologische Stellung des Vorkommens erklären.Herrn Prof. Dr.Carl W. Correns zum 70. Geburtstag gewidmet.  相似文献   

Computer modelling of clouds at Kleiner Feldberg     

R. N. Colvile  R. Sander  T. W. Choularton  K. N. Bower  D. W. F. Inglis  W. Wobrock  D. Schell  I. B. Svenningsson  A. Wiedensohler  H. -C. Hansson  A. Hallberg  J. A. Ogren  K. J. Noone  M. C. Facchini  S. Fuzzi  G. Orsi  B. G. Arends  W. Winiwarter  T. Schneider  A. Berner 《Journal of Atmospheric Chemistry》1994,19(1-2):189-229

The airflow, cloud microphysics and gas- and aqueous-phase chemistry on Kleiner Feldberg have been modelled for the case study of the evening of 1 November 1990, in order to calculate parameters that are not easily measured in the cloud and thus to aid the interpretation of the GCE experimental data-set. An airflow model has been used to produce the updraught over complex terrain for the cloud model, with some care required to ensure realistic modelling of the strong stable stratification of the atmosphere. An extensive set of measurements has been made self-consistent and used to calculate gas and aerosol input parameters for the model. A typical run of the cloud model has calculated a peak supersaturation of 0.55% which occurs about 20 s after entering cloud where the updraught is 0.6 m s^–1. This figure has been used to calculate the efficiency with which aerosol particles were scavenged; it is higher than that calculated by other methods, and produces a cloud with slightly too many droplets. A broad cloud droplet size spectrum has been produced by varying the model inputs to simulate turbulent mixing and fluctuations in cloud parameters in space and time, and the ability of mixing processes near cloud-base to produce a lower peak supersaturation is discussed. The scavenging of soluble gases by cloud droplets has been observed and departures from Henry's Law in bulk cloud-water samples seen to be caused by variation of pH across the droplet spectrum and the inability of diffusion to adjust initial distributions of highly soluble substances across the spectrum in the time available. Aqueous-phase chemistry has been found to play a minor role in the cloud as modelled, but circumstances in which these processes would be more important are identified.  相似文献